Geochemical, mineralogical records, and statistical approaches in establishing sedimentary in the environment of a Mediterranean coastal system: case of Sebkha El-Guettiate (southeastern Tunisia).

The current study was conducted within the context of the Holocene era in Sebkha El-Guettiate, located in southeastern Tunisia. The aim was to determine the factors influencing the geochemical and mineralogical composition of sediments and to elucidate the sedimentary characteristics of the Holocene within the Sebkha core. We examined a sediment core extending 100 cm from this Sebkha, subjecting it to comprehensive analysis to uncover its sedimentological, mineralogical, and geochemical properties. Several techniques were employed to strengthen and validate the connections between geochemical and mineralogical analyses, including X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and infrared (IR) spectroscopy, among others. Furthermore, statistical analyses utilizing principal component analysis (PCA) were applied to the results of the geochemical and mineralogical studies, aiding in the identification of patterns and relationships. A comprehensive mineralogical assessment of the core's sediments revealed the presence and interpretation of carbonate minerals, evaporite minerals, and detrital minerals. Through the application of infrared (IR) spectrometer techniques to all sediment samples, we gained insight into the mineralogical components and the distribution of key elements such as quartz, kaolinite, calcite, feldspar, and organic carbon. The geochemical composition demonstrated a clear dominance of silica (SiO2), accompanied by fluctuations in carbonate percentages (CaCO3). The prominent major elements, primarily magnesium (Mg) and calcium (Ca) originating from dolomitization, sodium (Na) and chlorine (Cl) from halite, and calcium (Ca) from gypsum, exhibited varying levels. Results from Rock-Eval 6 pyrolysis indicated that the organic matter within the sediments is generally a mixture of terrestrial and aquatic origins. This study provides practical information that underscores the diverse origins contributing to Sebkha sediment formation, often influenced by saline systems.

Sediment quality and environmental risk assessment in a Mediterranean coastal system using geochemical and multivariate statistical analyses: the case of Boughrara Lagoon (southeastern Tunisia).

Coastal ecosystems are the most vulnerable to natural and anthropogenic pressures which should be assessed using various chemical and ecological indicators. Our study aims to provide practical monitoring of anthropogenic pressures related to metal discharges in coastal waters for identifying potential ecological deterioration. The spatial variability of various chemical elements concentrations and their main sources were determined in the surficial sediments of a Mediterranean coastal area submitted to high anthropogenic pressure, the semi-enclosed Boughrara Lagoon located in southeastern Tunisia, by conducting several geochemical and multi-elemental analyses. The grain size and the geochemical analyses both suggested a marine influence of the sediment inputs in the north of the area (near Ajim channel), whereas continental and aeolian features dominated the sedimentary inputs in the southwestern lagoon. This last area was also characterized by the highest concentrations of metals, in particular Pb (4.45-173.33 ppm), Mn (68.45-1469.27 ppm), Cu (7.64-134.26 ppm), Zn (28.74-244.79 ppm), Cd (0.11-2.23 ppm), Fe (0.5-4.9%), and Al (0.7-3.2%). By referring to background crustal values and the contamination factor calculations (CF), the lagoon is considered as highly polluted for Cd, Pb, and Fe (3 < CF < 6). Three possible sources of pollution were identified: phosphogypsum effluents (P, Al, Cu, and Cd), the ex-Pb mine (Pb and Zn), and the cliff weathering and streams input from the red clay quarry (Fe). Furthermore, pyrite precipitation was identified for the first time in the Boughrara lagoon, suggesting the occurrence of anoxic conditions in this lagoon.